Decoupling of As and Fe release to Bangladesh groundwater under reducing conditions. Part I: Evidence from sediment profiles     

A. Horneman  A. van Geen  P.E. Mathe  R.K. Dhar  M.A. Hoque  M. Shamsudduha  K.M. Ahmed 《Geochimica et cosmochimica acta》2004,68(17):3459-3473

This study reexamines the notion that extensive As mobilization in anoxic groundwater of Bangladesh is intimately linked to the dissolution of Fe oxyhydroxides on the basis of analyses performed on a suite of freshly collected samples of aquifer material. Detailed sediment profiles extending to 40 to 70 m depth below the surface were obtained at six sites where local groundwater As concentrations were known to span a wide range. The sediment properties that were measured include (1) the proportion of Fe(II) in the Fe fraction leached in hot 1.2 N HCl, (2) diffuse spectral reflectance, and (3) magnetic susceptibility.In parallel with local concentrations of dissolved As ranging from <5 to 600 μg/L, Fe(II)/Fe ratios in shallow (gray) Holocene sands tended to gradually increase with depth from values of 0.3 to 0.5 to up to 0.9. In deeper (orange) aquifers of presumed Pleistocene age that were separated from shallow sands by a clay layer and contained <5 μg/L dissolved As, leachable Fe(II)/Fe ratios averaged ∼0.2. There was no consistent relation between sediment Fe(II)/Fe and dissolved Fe concentrations in groundwater in nearby wells. The reflectance measurements indicate a systematic linear relation (R² of 0.66; n = 151) between the first derivative transform of the reflectance at 520 nm and Fe(II)/Fe. The magnetic susceptibility of the shallow aquifer sands ranged from 200 to 3600 (x 10⁻⁹ m³/kg SI) and was linearly related (R² of 0.75; n = 29) to the concentrations of minerals that could be magnetically separated (0.03 to 0.79% dry weight). No systematic depth trends in magnetic susceptibility were observed within the shallow sands, although the susceptibility of deeper low-As aquifers was low (up to ∼200 × 10⁻⁹ m³/kg SI).This set of observations, complemented by incubation results described in a companion paper by van Geen et al. (this volume), suggests that the release of As is linked to the transformation of predominantly Fe (III) oxyhydroxide coatings on sand particles to Fe(II) or mixed Fe(II/III) solid phases with a flatter reflectance spectrum such as siderite, vivianite, or magnetite, without necessarily resulting in the release of Fe to groundwater. The very low As/Fe ratio of magnetically separated minerals compared to the As/Fe of bulk acid leachate (2 vs. 40 10⁻⁶, respectively) suggests that such a transformation could be accompanied by a significant redistribution of As to a mobilizable phase on the surface of aquifer particles.  相似文献   

Mitigation of liquefaction and associated ground deformations by stone columns   总被引：3，自引：0，他引：3  

Korhan Adalier  Ahmed Elgamal   《Engineering Geology》2004,72(3-4):275-291

Soil liquefaction and associated ground failures have been a major source of damage during the past earthquakes. The risk of liquefaction and associated ground deformation can be reduced by various ground-improvement methods including the stone column (gravel drain) technique. This paper presents the current state of the stone column technologies as a liquefaction countermeasure. A comprehensive review is provided aiming to: (a) identify key considerations for the general use of stone columns as a liquefaction countermeasure, (b) provide insights for design and construction, (c) compile the latest research developments, and (d) identify sources of useful information. Case histories of field applications and observed field performance are cited to portray different stone column applications and observed effectiveness. The paper identifies areas where more research is needed and includes recommendations for future research and development.  相似文献   

Le Silurien de la région d'Oulad Abbou (Meseta occidentale,Maroc) : une sédimentation péritidale sous contrôle tectonique     

Ahmed Attou  Naima Hamoumi 《Comptes Rendus Geoscience》2004,336(9):767-774

In the Oulad Abbou syncline, western coastal Meseta, the Silurian deposits exhibit siliciclastic or mixed siliciclastic/carbonate tidal facies that recorded alkaline basalt flows and syn-sedimentary deformations. These facies are staked into peritidal shallowing upward sequences reflecting the evolution from an infratidal to a supratidal environment. These sequences recorded low-amplitude and high-frequency sea-level variations. The built-up of these rhythmic sequences is related to distensive tectonic that allowed the development of isolated platform from extensive siliciclastic influx. This tectonic event is well recorded in the palaeogeographic evolution of the northern Gondwana platform during the Lower Palaeozoic time. To cite this article: A. Attou, N. Hamoumi, C. R. Geoscience 336 (2004).  相似文献   

Interpretation of magnetic data using analytic signal derivatives     

Ahmed Salem 《Geophysical Prospecting》2005,53(1):75-82

This paper develops an automatic method for interpretation of magnetic data using derivatives of the analytic signal. A linear equation is derived to provide source location parameters of a 2D magnetic body without a priori information about the nature of the source. Then using the source location parameters, the nature of the source can be ascertained. The method has been tested using theoretical simulations with random noise for two 2D magnetic models placed at different depths with respect to the observation height. In both cases, the method gave a good estimate for the location and shape of the sources. Good results were obtained on two field data sets.  相似文献   

Modelling load–displacement response of driven piles in cohesionless soils under tensile loading     

Ahmed Shlash Alawneh   《Computers and Geotechnics》2005,32(8):578-586

A new methodology for deriving the uplift load–displacement response of long driven piles in cohesionless soils is proposed. This method accounts for the effects of the friction fatigue processes during pile driving and the existence of locked-in residual stresses at the end of pile driving before commencing the pile load test. A hyperbolic formulation is utilized to simulate the nonlinear load transfer curves (the so-called t–z curves). The utility of this technique is demonstrated for a field pullout load test on a driven pile in sand. Predicted and measured load–displacement curves showed good agreement, indicating that this approach yields reasonable results as long as representative input parameters are employed.  相似文献   

Present environment and historic changes from the record of lake sediments, Dhaka City, Bangladesh   总被引：1，自引：0，他引：1  

Faruque Ahmed  M. Hawa Bibi  M. Hussain Monsur  Hiroaki Ishiga 《Environmental Geology》2005,48(1):25-36

Changes in the urban environment of Dhaka City have been evaluated from the geochemical compositions of bottom sediments from two lakes, Gulshan-1 and –2. Abundances of Pb, Zn, Fe₂O₃ and total sulfur in a Gulshan-1 core gradually increase toward the sediment–water interface. Three stages of condition change can be recognized in Gulshan-1, based on trace metal concentration patterns. The basal Stage I corresponds to background Dhaka sedimentation, whereas gradual increase in Stage II represents the beginning of pollution. Marked increases in Pb and Zn in Stage III reflect rapid urban development and increased emissions to the atmosphere. The condition of the Dhaka environment is compared to that of Japan based on Zn–Fe₂O₃ and Pb–Fe₂O₃ relations. Zn–Fe₂O₃ ratios in Stage I Dhaka sediments are similar to normal Japanese sediments, whereas Stage II data lie on the same trend as Japan urban sediments. Dhaka Stage III samples have greater Zn:Fe₂O₃ ratios than Japanese urban sediments, suggesting Zn pollution from poorly-controlled industrial sources. In contrast, the Dhaka Pb–Fe₂O₃ trend lies between normal and urban Japanese sediments. Although vehicle emissions in Dhaka are now significant, the data suggest that Pb pollution from this source remains in its early stages.  相似文献   

Geochemistry and Depositional Setting of Fort Munro Formation, Middle and Lower Indus Basins, Pakistan     

ShahidNaseem ShamimAhmedSheikh ErumBashir KhaulaShirin 《中国地质大学学报(英文版)》2005,16(2):160-169

INTRODUCTION Theinteractionofcomplextectonicphasesinthe IndusbasinduringtheCretaceoushasimpartedascal lopedoutlineinthesedimentarysequences.Thedevel opmentofdiversifiedsedimentaryformationsduringthe Cretaceousensuresexcellentsources(SembarandGoru formations)andreservoirs(MoghalKotandPabfor mations)forhydrocarbons.Numerousplaysandpros pectsofhydrocarbonareassociatedwiththeCretaceous system,consequentlytheIndusbasinisattractiveto petroleumexplorationcompaniesinPakistan(Sheikh andNa…  相似文献   

Spatial pattern of variation in populations of Acacia nilotica in semi-arid environment     

S. Mahmood  A. Ahmed  A. Hussain  M. Athar 《International Journal of Environmental Science and Technology》2005,2(3):193-199

Variability among populations was analyzed in five provenances of Acacia nilotica from spatially variable habitats. Populations of A. nilotica developed in response to their habitat conditions. The level of variability was significantly high among the populations. Phenotypic variability was extremely high for leaf and stipular spine characteristics. The nature of morphological variability for vegetative traits appeared environmentally controlled. The differentiation of leaf and stipular spine expression seems to have an adaptive significance for the species in terms of water economy. Although, seed and pod characteristics are genetically controlled showing a lower proportion of variability but these traits supported r and k-selection that may allow the species to survive under a wide array of contrasting habitats. The study suggested that populations of A. nilotica are differentiated in relation to the heterogeneity of environment. These populations became adapted to their habitat through the variability of morphological expressions. The morphologically differentiated populations of the species had allowed them to maintain themselves in a wide array of environmental situations enabling A. nilotica to occupy ample ecological ranges.  相似文献   

Integration of aquifer geology,groundwater flow and arsenic distribution in deltaic aquifers – A unifying concept          下载免费PDF全文

Mohammad A. Hoque  William G. Burgess  Kazi M. Ahmed 《水文研究》2017,31(11):2095-2109

Groundwater arsenic (As) presents a public health risk of great magnitude in densely populated Asian delta regions, most acutely in the Bengal Basin (West Bengal, India and Bangladesh). Research has focused on the sources, mobilisation, and heterogeneity of groundwater As, but a consistent explanation of As distribution from local to basin scale remains elusive. We show for the Bengal Aquifer System that the numerous, discontinuous silt‐clay layers together with surface topography impose a hierarchical pattern of groundwater flow, which constrains As penetration into the aquifer and controls its redistribution towards discharge zones, where it is re‐sequestered to solid phases. This is particularly so for the discrete periods of As release to groundwater in the shallow subsurface associated with sea level high‐stand conditions of Quaternary inter‐glacial periods. We propose a hypothesis concerning groundwater flow ( S ilt‐clay layers I mpose H ierarchical groundwater flow patterns constraining A rsenic progression [SIHA]), which links consensus views on the As source and history of sedimentation in the basin to the variety of spatial and depth distributions of groundwater As reported in the literature. SIHA reconciles apparent inconsistencies between independent, in some cases contrasting, field observations. We infer that lithological and topographic controls on groundwater flow, inherent to SIHA, apply more generally to deltaic aquifers elsewhere. The analysis suggests that groundwater As may persist in the aquifers of Asian deltas over thousands of years, but in certain regions, particularly at deeper levels, As will not exceed low background concentrations unless groundwater flow systems are short‐circuited by excessive pumping.  相似文献   

Geotechnical Characteristics of Stabilized Sabkha Soils from the Egyptian–Libyan Coast     

Ahmed M. A. Nasr 《Geotechnical and Geological Engineering》2015,33(4):893-911

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